A 3D 3d-4f heterometallic coordination polymer: Synthesis, crystal structure and properties

作者:Liu, Guang-Xiang*; Wang, Yan; Huang, Liang-Fang; Kong, Xue-Jun; Chen, Hong
来源:Journal of Inorganic and Organometallic Polymers and Materials, 2008, 18(3): 358-363.
DOI:10.1007/s10904-008-9212-1

摘要

A three-dimensional heterometallic coordination polymer formulated as Sm2Zn2( BIPA) 5(H2O) 2 ( 1) (H(2)BIPA = 5-bromoisophthalic acid) was synthesized by hydrothermal reaction of H2BIPA with Sm2O3 and Zn(NO3)(2). Complex 1 shows an 8-connected (3(6).4(18).5(3).6) topological network. The thermal analysis of complex 1 has been measured and discussed. Additionally, the photoluminescent property of complex 1 was investigated.