A Three-Interpenetrating Cobalt(II) Coordination Polymer Based on 4,4 '-Azodibenzoic acid and 4,4 '-Bipyridine: Solvothermal Synthesis, Crystal Structure and Thermal Stability Properties

作者：Han Yin-Feng^*; Liu Tao; Duan Wen-Zeng; Wu Ren-Tao; Li Ji-Kun; Li Xiao-Yan

来源：Chinese Journal of Inorganic Chemistry, 2012, 28(1): 149-152.

• Co(II) coordination polymer
• azodibenzoic acid
• crystal structure
• interpenetrate

A Co coordination polymer, [Co(ADB)(H(2)ADB)(BPY)]center dot 2CH(4)OH (H(2)ADB=4,4'-azodibenzoic acid, BPY=4,4'-bipyridine), has been synthesized by solvothermal reaction and characterized by clement analysis, IR spectra, TGA curve and single-crystal X-ray diffraction. The crystallographic data shows that the title complex crystallizes in monoclinic system, space group C2/c. Each Co(II) is six-coordinated to four O atoms from two ADB(2-), two H(2)ADB ligands, two nitrogen atoms from two BPY molecules at forms distorted octahedral coordination geometry. The Co2+ ions are interlinked by the ADB(2-), H(2)ADB and BPY to yield 2D net. CCDC: 745404.

• 出版日期2012-1
• 单位泰山学院