Discovery of gamma-MnP4 and the Polymorphism of Manganese Tetraphosphide

作者：Henge Dennis B; Hermus Martin; Litterscheid Christian F; Wagner Norbert; Beck Johannes; Albert Barbara^*; Brgoch Jakoah

来源：Inorganic Chemistry, 2015, 54(17): 8761-8768.

DOI：10.1021/acs.inorgchem.5b01372

A new polymorph of MnP4 was prepared by reaction of the elements via chemical vapor transport with iodine as transporting agent. The crystal structure was refined using single-crystal diffraction data (space group Cc, no. 9, a = 5.1049(8) angstrom, b = 10.540(2) angstrom, c = 10.875(2) angstrom, beta = 93.80(2)degrees). The phase is called gamma-MnP4 as it is isostructural with gamma-FeP4. It is the fourth reported binary polymorph in the MnP4, system, all of which are stacking variants of nets built with manganese and phosphorus atoms. In gamma-MnP4, there are two Mn-Mn distances (2.93 and 3.72 angstrom) arising from a Peierls-like distortion effectively forming Mn-2 dumbbells in the structure. Magnetic and electrical conductivity measurements show diamagnetism and a small anisotropic band gap (100-200 meV) with significantly enhanced conductivity along the crystallographic a axis. Calculations of the electronic and vibrational (phonon) structures show the P-P and Mn-P bonds within the nets are mainly responsible for the stability of the phase. The similar bonding motifs of the polymorphs give rise to the existence of numerous dynamically stable variants. The calculated Helmholtz energy shows the polymorph formation to be closely tied to temperature with the 6-MnP4 structure favorable at low temperatures, the 2-MnP4 favorable between approximately 800 and 2000 K, and 8-MnP4 preferred at high temperatures.

• 出版日期2015-9-7