A photocatalytic graphene quantum dots-Cu2O/bipolar membrane as a separator for water splitting

作者：Liu, Xian; Jian, Xuan; Yang, Huimin; Song, Xiuli; Liang, Zhenhai^*

来源：New Journal of Chemistry, 2016, 40(4): 3075-3079.

DOI：10.1039/c5nj03604f

• LITHIUM-ION BATTERIES
• BIPOLAR MEMBRANE
• PHOTOVOLTAIC DEVICES
• NANO-ZNO
• DOTS
• CELLS
• ELECTRODIALYSIS
• PERFORMANCE
• LAYER
• NANOCOMPOSITES

Graphene quantum dots-Cu2O (GQDs-Cu2O) is introduced to a bipolar membrane (BPM) interlayer and shown to be a novel, efficient water dissociation catalyst. This paper reports the use of the GQDs-Cu2O/BPM composite as a separator to prevent the crossover of hydrogen and oxygen. Under reverse bias and sunlight irradiation conditions, GQDs-Cu2O/BPM exhibits lower membrane resistance than BPM. GQDs-Cu2O/BPM also minimizes pH gradient formation, resulting in a decreased potential loss with respect to that of BPM. The efficiency of GQDs-Cu2O/BPM as a diaphragm in H-2 generation and energy conservation was assessed. GQDs-Cu2O/BPM was found to be 88.6% and 14.5% more efficient than BPM in H-2 generation at the current density of 90 mA cm(-2) and under sunlight irradiation, respectively. The composite also saved about 22.6% energy with respect to that of BPM at 90 mA cm(-2).

• 出版日期2016
• 单位太原理工大学