A tetracopper(II) complex of 4,6-dimethyl-2-hydroxy-isophthalic acid comprising a dimer of dinuclear subunits

作者：Crane JD^*; McLaughlin A

来源：Inorganic Chemistry Communications, 2004, 7(4): 499-501.

DOI：10.1016/j.inoche.2004.01.015

• copper complexes
• carboxylate ligands
• tetranuclear complexes

The dinucleating ligand 4,6-dimethyl-2-hydroxy-isophthalic acid, H3L, forms the tetracopper(II) Complex Cu4L2(O2CCH3)(2)(py)(4)(CH(3)0OH)(2) 1. The single crystal X-ray structure of 1.2CH(3)OH reveals that this complex is a carboxylate bridged dimer of dinuclear copper(II) subunits. in which the copper(II) centres adopt square-based pyramidal geometries.

• 出版日期2004-4