Application of sol-gel based octyl-functionalized mesoporous materials coated fiber for solid-phase microextraction

作者：Wang Xuemei; Rao Honghong; Lu Xiaoquan; Du Xinzhen^*

来源：Talanta, 2013, 105: 204-210.

DOI：10.1016/j.talanta.2012.11.074

• Solid-phase microextraction
• Sol-gel technology
• High-performance liquid chromatography
• Polycyclic aromatic hydrocarbons

Octyl-functionalizd mesoporous SBA-15 was first used as precursor and selective stationary phase to prepare solid-phase microextraction (SPME) fiber by using the sol-gel technique. The new SPME coating possessed honeycomb-like porous structure and rough surface and showed excellent chemical stability and longer life span (over 200 cycles of usage). The performance of the octyl-SBA-15-coated fiber was tested through extraction of eight polycyclic aromatic hydrocarbons (PAHs). The results showed that the home-made SPME fiber exhibited higher extraction efficiency compared with the commercial SPME (30 mu m and 100 mu m PDMS) fibers. For PAHs analysis, the new fiber showed good precision (< 4.8%), low detection limits (0.024-0.050 mu g/L), and wide linearity (0.1-200 mu g/L) under the optimized conditions. The repeatability of fiber-to-fiber and batch-to-batch was 3.2-8.4% and 4.4-9.5%, respectively. The method was applied to simultaneous analysis of eight PAHs with satisfactory recoveries in different spiking levels, which were 85.7-103.4% (10 mu g/L) and 87.0-107.2% (50 mu g/L) for water samples and 76.2-89.0% (10 mu g/g) and 75.6%-91.2% (50 mu g/g) for soil samples, respectively.

• 出版日期2013-2-15
• 单位西北师范大学