Autocatalytic demetalation of a Zn(salphen) complex provoked by unprotected N-heterocycles

作者:Escudero Adan Eduardo C; Benet Buchholz Jordi; Kleij Arjan W*
来源:Dalton Transactions, 2008, (6): 734-737.
DOI:10.1039/b713039b

摘要

The interaction of Zn(salphen) complex 1a with biologically important structures such as (benz)imidazoles and purine has been studied and revealed in the case of unprotected purine and (benz) imidazole derivatives a demetalated product, whereas for structurally related 1-methyl-(benz)imidazole the formation of 1 : 1 coordination complexes was evidenced by NMR, MS and X-ray crystallography.

  • 出版日期2008