A Pair of 3D Homochiral Coordination Polymers with Open Channels Constructed by Lactic Acid Derivative Ligands and In-situ Formed Anions

作者：Xu Zhong-Xuan^*; Ma Yu-Lu

来源：Chinese Journal of Structural Chemistry, 2017, 36(4): 671-678.

DOI：10.14102/j.cnki.0254-5861.2011-1348

• homochiral coordination polymers
• lactic acid derivative ligand
• open channel

With the help of in-situ formed CH(3)COO(-)anion, a pair of 3D homochiral coordination polymers with open channels were constructed by the assembly of lactic acid derivative ligands, 1.4-DIB ligands and Cd(II) ions, namely inverted right perpendicular Cd-3((R)-CIA)(2)(CH3CO2)(2)(1.4-DIB)(2)(H2O)(2) inverted left perpendicular center dot x(Guest) (1-D) and [Cd-3((S)-CIA)(2)(CH3CO2)(2)(1.4-DIB)(2)(H2O)(2)]center dot x(Guest) (1-L). They contain 1D interesting ladder-like Cd-(R)-CIA(3)(-)chains and exhibit SHG-active behavior and photoluminescent property.

• 出版日期2017-4-15
• 单位云南大学; 遵义师范学院