Adsorption of Reactive Red 2 from aqueous solutions using Fe3O4 nanoparticles prepared by co-precipitation in a rotating packed bed

作者：Lin Chia Chang; Lin Yu Shung; Ho Jui Min

来源：Journal of Alloys and Compounds, 2016, 666: 153-158.

DOI：10.1016/j.jallcom.2016.01.015

• Rotating packed bed
• Fe3O4
• Nanoparticles
• Reactive Red 2
• Adsorption

A rotating packed bed (RPB) that was operated at a rotating speed of 1800 rpm with liquid flow rates of 0.5 L/min was used to prepare Fe3O4 nanoparticles (RPB-Fe3O4). The RPB-Fe3O4 had a smaller average size and a narrower size distribution than the Fe3O4 that was obtained from Aldrich, and so had a greater capacity to adsorb RR2. The effects of pH, Fe3O4 dosage, initial RR2 concentration, and temperature on the adsorption of RR2 were examined experimentally using RPB-Fe3O4. A thermodynamic study revealed that the adsorption process was spontaneous and exothermic. The adsorption behavior was more consistent with the Langmuir model than with the Freundlich model, and the maximum adsorption capacity was 97.8 mg/g. At pH 3, 25 degrees C, an Fe3O4 dosage of 0.30 g/L, and an initial RR2 concentration of 10 mg/L, RPB-Fe3O4 effectively adsorbed RR2 with a removal efficiency of approximately 95% in 10 min. These promising results clearly reveal the potential of RPB-Fe3O4 for use in the effective removal of dyes from aqueous solutions.

• 出版日期2016-5-5
• 单位长春大学