High-precision absolute lattice parameter determination of SrTiO3, DyScO3 and NdGaO3 single crystals

作者:Schmidbauer Martin*; Kwasniewski Albert; Schwarzkopf Jutta
来源:Acta Crystallographica Section B-Structural Science, 2012, 68(1): 8-14.
DOI:10.1107/S0108768111046738

摘要

The lattice parameters of three perovskite-related oxides have been measured with high precision at room temperature. An accuracy of the order of 10(-5) has been achieved by applying a sophisticated high-resolution X-ray diffraction technique which is based on the modified Bond method. The results on cubic SrTiO3 [a = 3.905268 (98) angstrom], orthorhombic DyScO3 [a = 5.442417 (54), b = 5.719357 (52) and c = 7.904326 (98) angstrom], and orthorhombic NdGaO3 [a = 5.428410 (54), b = 5.498407 (55) and c = 7.708878 (95) angstrom] are discussed in view of possible systematic errors as well as non-stoichiometry in the crystals.

  • 出版日期2012-2