A new nickel(II) complex [NiL]center dot 1.5CH(2)Cl(2), where H2L is 14,25-dichloro-2,11-diphenyl-tetracyclo[20.4.0.0(4,9).0(12,17)]hexacosa- 2,10,12,14,16,22,24,26-octaene-19,20-dione

作者：Zhang RH; Yang GM^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2005, 61: M2434-M2435.

DOI：10.1107/S1600536805034628

In the new nickel(II) complex [14,25-dichloro-2,11-diphenyl-tetracyclo[ 20.4.0.0(4,9).0(12,17)]hexacosa-2,10,12,14,16,22,24,26-octaene- 19,20-dionato(2-)]nickel(II)dichloromethane sesquisolvate, [Ni(C34H26Cl2N4O2)]center dot 1.5CH(2)Cl(2), the nickel(II) ion is four-coordinate and displays approximately square-planar coordination geometry. It binds to two deprotonated oxamide N atoms and two imine N atoms of the macrocyclic ligand. The C atom of one of the two dichloromethane solvent molecules lies on a twofold axis.

• 出版日期2005-11
• 单位南开大学