Alkali halides based on nano-alumina as positive and negative ion source for ion mobility and mass spectrometry

作者：Shahraki Hassan; Tabrizchi Mahmoud^*; Farrokhpour Hossein

来源：Journal of the Iranian Chemical Society, 2018, 15(4): 863-870.

DOI：10.1007/s13738-017-1285-8

• Nano-gamma-alumina (Al2O3)
• Ion source
• Ion mobility spectrometry
• Alkali ions
• Halide ions

In this work, a new long-life alkali ion source is proposed that is based on alkali halide salts doped in nano-gamma-alumina (Al2O3). Depending on the polarity, the ion source produces both alkali and halide ions. The source was characterized using different techniques such as scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), fourier transform infrared (FT-IR), and ion mobility spectrometry (IMS). SEM images confirm a strong interaction between the alkali halide (MX) and nano-gamma-alumina. The average particle size of the doped nanoparticles was calculated to be 44 nm by TEM. Formation of new phases (KAlCl2O and K3AlF6) was confirmed by XRD and that of Al-O-K group in the synthesized particles by FT-IR. Alkali and halide ion peaks were observed by IMS in the positive and negative modes, respectively. The lifetime of the ion source for different alkali halides was measured to range from 216 to 960 h. The total ion current emitted from the source was about 2 A mu A, while it was 12 nA at the collector plate of the IMS. Finally, application of the new source in ion mobility spectrometry was demonstrated by observing ion mobility spectra of compounds ionized via cation and anion attachment reaction.

• 出版日期2018-4