AN ENERGY TRANSFER CHEMILUMINESCENT REACTION OF LOPHINE PEROXIDES

作者：Kimura Masaru^*; Akaki Kaoru; Mishima Yasunobu; Araki Hiroyuki; Fukai Takeshi

来源：Heterocycles, 2009, 79(1): 1019-1024.

DOI：10.3987/COM-08-S(D)79

• Chemiluminescence
• Energy Transfer
• Electron Transfer
• Imidazole
• Peroxide

A linear correlation existed between the absorption energy of activators (E(o-o)'s) and the sensitized chemiluminescence (CL) yields (phi(SCL)'S) for the CL reaction of lophine peroxides (2a and 2b), whereas a linear correlation did not exist between their oxidation potentials (E(ox)'s) and phi(SCL)'S. Based on the finding, an energy transfer mechanism is likely rather than an electron transfer mechanism like the CIEEL mechanism.

• 出版日期2009-4-1