Nanoporous Ru as a Carbon- and Binder-Free Cathode for Li-O-2 Batteries

作者：Liao Kaiming^*; Zhang Tao; Wang Yongqing; Li Fujun; Jian Zelang; Yu Haijun; Zhou Haoshen

来源：Chemsuschem, 2015, 8(8): 1429-1434.

DOI：10.1002/cssc.201403371

• carbon- and binder-free cathode
• charging potential
• Li-O-2 battery
• mesoporous materials
• ruthenium

Porous carbon-free cathodes are critical to achieve a high discharge capacity and efficient cycling for rechargeable Li-O-2 battery. Herein, we present a very simple method to directly grow nanoporous Ru (composed of polycrystalline particles of approximate to 5nm) on one side of a current collector of Ni foam via a galvanic replacement reaction. The resulting Ru@Ni can be employed as a carbon- and binder-free cathode for Li-O-2 batteries and delivers a specific capacity of 3720mAhg(Ru)(-1) at a current density of 200mAg(Ru)(-1). 100cycles of continuous discharge and charge are obtained at a very narrow terminal voltage window of 2.75 approximate to 3.75V with a limited capacity of 1000mAhg(Ru)(-1). The good performance of the nanoporous Ru@Ni cathode can be mainly attributed to the effective suppression of the by-products related to carbon or binder, the good adhesion of the catalyst to the current collector, and the good permeation of O-2 and electrolyte into the active sites of the nanoporous Ru with the open pore system. This new type electrode provides a snapshot toward developing high-performance carbon- and binder-free Li-O-2 batteries.

• 出版日期2015-4-24