A highly modular and convergent approach for the synthesis of stimulant-responsive heteroligated cofacial porphyrin tweezer complexes

作者：Oliveri Christopher G; Nguyen SonBinh T^*; Mirkin Chad A

来源：Inorganic Chemistry, 2008, 47(7): 2755-2763.

DOI：10.1021/ic702150y

The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)(2)Cl](2) to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.

• 出版日期2008-4-7
• 单位西北大学