A three-dimensional metal-organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies

作者：Guo, Zhiyong; Yu, Jiangbo; Li, Guanghua; Si, Zhenjun; Guo, Huadong; Zhang, Hongjie^*

来源：CrystEngComm, 2009, 11(11): 2254-2256.

DOI：10.1039/b903932e

• SECONDARY BUILDING UNITS
• HIGH H-2 ADSORPTION
• HYDROGEN STORAGE
• COORDINATION-FRAMEWORK
• PERMANENT POROSITY
• POROUS MATERIAL
• DESIGN
• SITES
• CARBOXYLATES
• SEPARATION

A novel metal-organic framework [Cu-3(m-TATB)(2)Py(CH3OH)(2)] (1) constructed of a triazine-based trigonal-planar ligand, 3,3',3 ''-s-triazine-2,4,6- triyltribenzoate (m-H(3)TATB), has been synthesized and structurally characterized. Compound 1 features three-dimensional (3D) channels and cavities together, and exhibits high carbon dioxide sorption at normal pressure.

• 出版日期2009
• 单位中国科学院; 吉林大学; 中国科学院长春应用化学研究所; 无机合成与制备化学国家重点实验室; 稀土资源利用国家重点实验室