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A three-dimensional metal-organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies
Guo Zhiyong
Yu Jiangbo
Li Guanghua
Si Zhenjun
Guo Huadong
Zhang Hongjie
CrystEngComm, 2009, 11(11): 2254-2256.
Summary
A novel metal-organic framework [Cu(3)(m-TATB)(2)Py(CH(3)OH)(2)] (1) constructed of a triazine-based trigonal-planar ligand, 3,3',3 ''-s-triazine-2,4,6- triyltribenzoate (m-H(3)TATB), has been synthesized and structurally characterized. Compound 1 features three-dimensional (3D) channels and cavities together, and exhibits high carbon dioxide sorption at normal pressure.
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