Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

作者：Ma BQ; Mulfort KL; Hupp JT^*

来源：Inorganic Chemistry, 2005, 44(14): 4912-4914.

DOI：10.1021/ic050452i

The reaction of Zn(NO3)(2)-6H(2)O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

• 出版日期2005-7-11
• 单位西北大学