Ionothermal synthesis and characterization of a 3-D (4,8)-connected porous anionic metal-organic framework entrapped with 1-D [K2(H2O)6] chains

作者：Ji, Wen-Juan; Zhai, Quan-Guo^*; Hu, Man-Cheng; Li, Shu-Ni; Jiang, Yu-Cheng; Wang, Yan

来源：Inorganic Chemistry Communications, 2008, 11(12): 1455-1458.

DOI：10.1016/j.inoche.2008.10.005

• Ionic liquid
• Ionothermal
• Coordination polymer
• 1,2,4,5-Benzenetetracarboxylate

A novel metal-organic coordination polymer, namely, {[K-2(H2O)(6)][Cd-3(1,2,4,5-BTC)(2)]}(n) (1) (1,2,4,5-BTC = 1,2,4,5-benzenetetracarboxylate), was synthesized in an ionothermal reaction by using an ionic liquid 1-ethyl-3-methylimidazolium bromide ([EMIM]Br) as solvent. Complex 1 features a novel 3-D (4.8)-connected porous anionic architecture constructed by linking trinuclear Cd subunits with 1,2,4.5-BTC4- ligands, which are further filled with 1-D [K-2(H2O)(6)] cationic chains.

• 出版日期2008-12
• 单位陕西师范大学