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摘要
The values of the variable component of chemical affinity (A-A (0)) are calculated and the relation between W (a kinetic parameter) and A-A (0) (a thermodynamic parameter) are established on the basis of experimental data on rates of the hydroformylation reaction (W) of isobutylene catalyzed by cobalt hydrocarbonyl, and of data on compositions of the gas and liquid phases of the reaction mixture. The linear phenomenological relations of nonequilibrium thermodynamics are found to describe the dependence of W on A-A (0) quite well at a conversion level of isobutylene of a parts per thousand yen50%.
- 出版日期2011-10
- 单位中国石油化工股份有限公司石油化工科学研究院
