A New Tetranuclear Cubane-like Ni(II) Complex Based on Schiff-base Ligand: Synthesis, Crystal Structure and Magnetic Properties

作者：Lian Qing-Yun; Hu Hang-Na; Li Can-Hui; Li Dong-Ping; Jiao Xiao-Yan; Li Yong-Xiu^*

来源：Chinese Journal of Structural Chemistry, 2017, 36(2): 273-279.

DOI：10.14102/j.cnki.0254-5861.2011-1289

• Ni(II) complex
• Schiff base
• crystal structure
• magnetic

A new Ni(II) cubane-like complex, namely, [Ni(L)(CH3OH)](4)center dot(CH3OH)(2), has been obtained via self-assembly of nickel(II) and Schiff base, where the ligand L is a raceme of (R)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl]-6-methoxy-phenol. X-ray diffraction analysis reveals that the complex shows a cubane-like [Ni4O4] cluster and similar coordination environment around the metallic centers. Magnetic measurements indicate there is ferromagnetic interaction within the Ni-4 cluster.

• 出版日期2017-2-15
• 单位南昌大学