Novel Phosphamide Additive to Improve Thermal Stability of Solid Electrolyte lnterphase on Graphite Anode in Lithium-lon Batteries

作者：Cao, Xia; Li, Yixiao; Li, Xiubin; Zheng, Jianming; Gao, Jun; Gao, Yuxing; Wu, Xiaobiao; Zhao, Yufen; Yang, Yong^*

来源：ACS Applied Materials & Interfaces, 2013, 5(22): 11494-11497.

DOI：10.1021/am4024884

• phosphamide
• solid electrolyte interface (SEI)
• safety
• lithium-ion batteries

In this communication, a novel electrolyte additive, N,N-diallyic-diethyoxyl phosphamide (DADEPA), is described for the first time to improve the thermal stability of lithiated graphite anode in Li-ion batteries. The differential scanning calorimetry (DSC) measurement demonstrated that when the graphite was lithiated in the 5% DADEPA-containing electrolyte, the heat generation decreased sharply by half as compared with the reference, whereas the onset temperature for the main exothermic process was postponed by 20 degrees C. Electrochemical and XPS analyses indicated that the distinctive improvement in thermal safety came from a new interfacial chemistry, in which phosphorus-containing ingredients was embedded during the initial forming of the interphase.

• 出版日期2013-11-27
• 单位厦门大学