科研之友
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摘要
A synthesis of fluorine-containing asparagine and glutamine analogues via palladium-catalyzed formate reduction of fluorinated carbonate esters is described. Primary amide moieties at the side-chain of asparagine and glutamine were successfully replaced with fluoroolefins, which are proposed to be aprotic mimics for amides due to their electronic properties.
- 出版日期2014-12
