Asymmetric zinc porphyrin-sensitized nanosized TiO2 for efficient visible-light-driven CO2 photoreduction to CO/CH4

作者：Li, Kan; Lin, Li; Peng, Tianyou^*; Guo, Yingying; Li, Renjie; Zhang, Jing

来源：Chemical communications, 2015, 51(62): 12443-12446.

DOI：10.1039/c5cc03812j

• PHOTOCATALYTIC HYDROGEN-PRODUCTION
• METAL-ORGANIC FRAMEWORK
• SOLAR-CELLS
• ANATASE TIO2
• REDUCTION
• HETEROJUNCTION
• TITANIA
• FUELS
• PHTHALOCYANINE
• IRRADIATION

Asymmetric zinc porphyrin (ZnPy) was synthesized and used to sensitize nanosized TiO2. The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase was observed from the ZnPy-sensitized TiO2 without loading noble metal, and the mechanism was discussed.

• 出版日期2015
• 单位武汉大学