A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation

作者:Miyamura Hiroyuki; Choo Gerald C Y; Yasukawa Tomohiro; Yoo Woo Jin; Kobayashi Shu*
来源:Chemical communications, 2013, 49(85): 9917-9919.
DOI:10.1039/c3cc46204h

摘要

The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.

  • 出版日期2013