A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

作者:Brusilowskij Boris; Neubacher Saskia; Schalley Christoph A*
来源:Chemical Communications, 2009, (7): 785-787.
DOI:10.1039/b819412b

摘要

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M(6)L(4) assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M(3)L(2) cages.

  • 出版日期2009