Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

作者:Mihaylov M; Chakarova K; Andonova S; Drenchev N; Ivanova E; Pidko E A; Sabetghadam A; Seoane B; Gascon J; Kapteijn F; Hadjiivanov K*
来源:Chemical communications, 2016, 52(7): 1494-1497.
DOI:10.1039/c5cc08677a

摘要

FTIR spectra of (CO2)-C-12 and (CO2)-C-12 + (CO2)-C-13 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)(2) species connected to two structural OH groups.

  • 出版日期2016