Direct microscopic observation of shish-kebab structure in high-temperature electrospun iPP fibers

作者:Liu, Shuangyang; Zhang, Feifei; Zheng, Guoqiang*; Dai, Kun; Liu, Chuntai*; Shen, Changyu; Guo, John Zhanhu
来源:Materials Letters, 2016, 172: 149-152.
DOI:10.1016/j.matlet.2016.02.111

摘要

Electrospinning is not only a technique to fabricate macroscopic fiber but also a method to control the microstructure. In this study, high-temperature solution electrospinning was used to prepare isotactic polypropylene (iPP) fibers. Scanning electron microscope (SEM) observation indicates that a single electrospun iPP fiber consists of many nano-fibrils. Based on SEM observation, these nano-fibrils are shish-kebab structure. Electrostatic elongational force involved in the electrospinning process is considered to be responsible for the development of shish-kebab structure.