Ammonia sensing properties of perylene diimides: Effects of core-substituted chiral groups

作者：Zhang, Shasha; Wang, Xuejuan; Huang, Yongwei^*; Zhai, Haiyan; Liu, Zhonghua^*

来源：Sensors and Actuators B: Chemical , 2018, 254: 805-810.

DOI：10.1016/j.snb.2017.07.185

• Perylenediimide derivatives
• Ammonia sensing properties
• Chiral groups
• Redox mechanism
• Structure-property relationships

The detection of ammonia vapor has strong implications for health, safety and environment. Herein, we reported on an high efficient chemiresistive sensor based on perylenediimide derivatives (PDIs) substituted by (S)-1-octyn-3-ol (SOT), (S)-3-butyn-2-ol (STB) and (S)-1-phenyl-2-propyn-1-ol (SPP) on 1, 7 bay positions. These PDIs devices exhibited high sensitivity, excellent selectivity and low detection limit towards ammonia vapor. In these materials, SPP showed the most efficient sensing performance, and the increment of current is 4 and 1.2 orders of magnitude higher than SOT and STB due to its lowest LUMO energy, uniform and continuous crystalline phase with pi-pi stacking distance of 3.28 angstrom. While the highest LUMO energy, poor crystallinity, and smaller pi-pi overlap as well as largest pi-pi distance of 3.35 angstrom resulted in the lowest performance of SOT device. It is expected that excellent sensing parameters and detailed analysis of the roles of core-substituted chiral groups will provide a basis protocol for the design of simple, low-power and high efficient PDIs sensors.

• 出版日期2018-1
• 单位河南大学