Application of equations of state to predict methane solubility under hydrate-liquid water two-phase equilibrium

作者：Huang, Ting^*; Li, Changjun; Jia, Wenlong; Peng, Yang

来源：Fluid Phase Equilibria, 2016, 427: 35-45.

DOI：10.1016/j.fluid.2016.06.049

• Methane solubility
• Gas hydrates
• Two-phase equilibrium
• Equations of state

Gas solubility in water under hydrate-liquid water (H-L-w) two-phase equilibrium is the foundation of gas hydrate kinetic study. It is significant for the simulation of multiphase pipeline flow, the stability and amount evaluation of natural gas hydrate resources in deep water as well as gas storage and separation. In the current work, thermodynamic models were established by combining van der Waals-Platteeuw theory with PR, VPT and TB equations of state separately, named as Model VPR, VVPT and VTB, to predict methane solubility in water under H-Lw equilibrium. The Henry's law was also included for comparison. Available experimental data in literature were collected to test the applicability of these equations of state. In order to improve the predicting accuracy, binary interaction parameters in the asymmetric contribution term of non-density-dependent (NDD) mixing rules were modified. Good agreements between predicted and experimental data were obtained by Model VVPT with the modified NDD mixing rules.

• 出版日期2016-11-15
• 单位西南石油大学