A novel 3D twofold interpenetrating microporous metal-organic framework containing 1D water tapes with cyclic pentamer units

作者：Liu Jian Qiang; Wang Yao Yu^*; Liu Ping; Wu Wei Ping; Wu Ya Pan; Zeng Xi Rui; Zhong Fan; Shi Qi Zhen

来源：Inorganic Chemistry Communications, 2007, 10(3): 343-347.

DOI：10.1016/j.inoche.2006.11.003

• interpenetration
• topology
• pentamer cluster
• crystal structure
• copper(II) complex

The self-assembly of Cu2+ ions with malate and 1,3-bis(4-pyridyl)propane (bpp) affords a 3D coordination polymer {[Cu(Hmal) (bpp) (.) 6H(2)O]}(n) (1) (malic acid = H(3)mal). The metal ions were interconnected by alpha- and beta-carboxylate of malate produce infinite [Cu(C4H4O5)](n) layers, which were further pillared by bridging ligand bpp molecules to form a 3D interpenetrating network. Of further interest, lattice water molecules form ID infinite water tapes in ID open cavities.

• 出版日期2007-3
• 单位西北大学; 井冈山大学