A new system for cyclohexane functionalization employing iron(III) catalysts and trichloroisocyanuric acid

作者:Gomes Clicia A; Lube Leonardo M; Fernandes Christiane; Franco Roberto W A; Resende Jackson A L C; Horn Adolfo Jr
来源:New Journal of Chemistry, 2017, 41(20): 11498-11502.
DOI:10.1039/c7nj01164d

摘要

Herein, dinuclear and mononuclear iron complexes were investigated as catalysts in the reaction of cyclohexane chlorination employing trichloroisocyanuric acid as oxidant. At 25 degrees C, the yields provided by both catalysts were similar (similar to 8%). However, at 50 degrees C, the mononuclear catalyst showed a better performance (34.4 +/- 1.8%) than the binuclear catalyst (24.4 +/- 1.0%).

  • 出版日期2017-10-21