Acceleration of the through space S-1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Forster J integral and its implication in the antenna effect in the photosystems

作者：Camus Jean Michel; Aly Shawkat M; Stern Christine; Guilard Roger^*; Harvey Pierre D

来源：Chemical Communications, 2011, 47(31): 8817-8819.

DOI：10.1039/c1cc12839f

The singlet k(ET) for cofacial beta-octaalkylporphyrin/bis(meso-aryl)-porphyrin dyads increases linearly with the gap between the donor-acceptor 0-0 fluorescence peaks at 77 K.

• 出版日期2011