摘要

Sea urchin-like Fe3O4@TiO2@Ag nanocomposites were controllably synthesized with tunable cavity size. Products were characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectra, X-ray diffraction and vibrating sample magnetometer. The sea urchin-like Fe3O4@TiO2@Ag nanocomposites have a diameter in the range of 100-200 nm and are monodisperse. As photocatalysts under UV irradiation, the as-synthesized nanocomposites display enhanced photocatalytic and recycling properties for the degradation of methylene blue. The photocatalytic performance is improved due to the synergistic effect of Fe3O4@TiO2@Ag nanoheterojunctions. The results showed that Fe3O4@TiO2@Ag composites exhibited high degree of crystallinity, excellent magnetic properties at room temperature. Moreover, these magnetic Fe3O4@TiO2@Ag nanocomposites can be completely removed from the dispersion with the help of magnetic separation and reused with little or no loss of catalytic activity. The enhanced photocatalytic activity and excellent chemical stability, in combination with the magnetic recyclability, makes this multifunctional nanostructure a promising candidate for remediation in aquatic environmental contamination in the future.