A novel 3D porous cadmium(II) MOF based on conjugated ligand with potential application for sensing small linear conjugated molecule

作者：Jin, Zhao; Zhao, Huanyu; Yang, Dongjiang; Yao, Xiangdong^*; Zhu, Guangshan

来源：Inorganic Chemistry Communications, 2012, 25: 74-78.

DOI：10.1016/j.inoche.2012.09.011

• 3, 4 ', 5-azobenzenetricarboxylate
• 3D open framework
• (3,3,6)-connected topology
• Luminescent properties
• Sensor

A novel 3D porous MOF [Cd-3(ABTA)(2)(DMF) (H2O)(2)] (1) (ABTA=3,4',5-azobenzenetricarboxylate) has been successfully synthesized by solvothermal reaction of Cd(NO3)(2)center dot 4H(2)O with ABTA. Single-crystal X-ray diffraction result reveals that complex 1 possesses a complicated 3D open framework with two intercrossed 1D channels along [200] and [11-1]. The photoluminescence experimental results of the complex in different solvents indicate that complex 1 has potential application in recognizing small linear conjugated molecule.

• 出版日期2012-11
• 单位青岛大学