A serendipitous phosphonocarboxylate complex of boron: when vessel becomes reagent

作者:Blazewska Katarzyna M; Haiges Ralf; Kashemirov Boris A; Ebetino Frank H; McKenna Charles E*
来源:Chemical communications, 2011, 47(22): 6395-6397.
DOI:10.1039/c1cc10876j

摘要

Under certain conditions, the phosphonocarboxylate analogue (3) of the bisphosphonate drug minodronate (4) in contact with borosilicate glassware reversibly forms an isolable dimer complex of boron, as revealed by the X-ray crystallographic structure of the (R,R/S,S) complex and supported by NMR and HRMS data.

  • 出版日期2011