The Actual Active Species of Sulfur-Modified Gold-Supported Palladium as a Highly Effective Palladium Reservoir in the Suzuki-Miyaura Coupling

作者：Hoshiya Naoyuki; Shuto Satoshi; Arisawa Mitsuhiro^*

来源：Advanced Synthesis & Catalysis, 2011, 353(5): 743-748.

DOI：10.1002/adsc.201000820

• C-C coupling
• combinatorial chemistry
• green chemistry
• heterogeneous catalysis
• palladium

The actual active species of the recently developed sulfur-modified, gold-supported palladium material, S-modified Au-supported Pd (SAPd), with one of the lowest Pd-releasing levels and high recyclability in the Suzuki-Miyaura coupling, was investigated. Also, SAPd was found to work repeatedly as an excellent Pd reservoir for liquid-phase combinatorial synthesis.

• 出版日期2011-3-28