An early-late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)(2)Pt-ZrCl4]

作者:Braunschweig Holger*; Radacki Krzysztof; Schwab Katrin
来源:Chemical communications, 2010, 46(6): 913-915.
DOI:10.1039/b921608a

摘要

The presented platinum zirconium adduct [(Cy3P)(2)Pt-ZrCl4] expands the range of known platinum metal adducts towards early-late heterobimetallics displaying the first unsupported dative transition metal bond; X-ray structure and DFT calculations gave an estimation about the bond strength and indicate a strong Pt-Zr bond.

  • 出版日期2010