A photo-stable and electrochemically stable poly(dumbbell-shaped molecules) for blue electrophosphorescent host materials

作者：Li Lu; Hu Tian Qing; Yin Cheng Rong; Xie Ling Hai^*; Yang Yang; Wang Chao; Lin Jin Yi; Yi Ming Dong; Ye Shang Hui; Huang Wei

来源：Polymer Chemistry, 2015, 6(6): 983-988.

DOI：10.1039/c4py01016g

Hindrance functionalization at the reactive sites makes p-stacked polymers highly stable for applications related to organic electroluminescent devices. Herein, a novel stable polymer host material, poly(3,6-bis( 9-phenylfluoren-9-yl)-9-vinyl-carbazole) (PVKDPF), has been designed and synthesized from dumbbell-shaped monomers by introducing two bulky 9-phenylfluorenyl moieties (PFMs) to the carbazole units. PVKDPF, with a high triplet energy level of 2.85 eV, shows outstanding thermal and morphological stability. Interestingly, as compared to its precursor, poly(N-vinylcarbazole) (PVK), PFMs-capped PVKDPF shows enhanced anti-photoaging against UV light, along with a much better electrochemical stability, without any obvious change even after repeated scanning during cyclic voltammetry. The prototype blue phosphorescent polymer light-emitting devices (PhPLEDs) using PVKDPF as the host and doped with the FIrpic guest exhibit excellent blue electroluminescence with the Commission Internationale de L'Eclairage (CIE) coordinate of (0.184, 0.381), luminous efficiency corresponding to 17.3 cd A(-1), and power efficiency corresponding to 9.0 lm W-1. Hindrance-capped dumbbell-shaped polymers are robust polymer semiconductors that can be used in mechatronic devices.

• 出版日期2015
• 单位南京邮电大学