Hydrothermal synthesis and crystal structure of a manganese(II) compound bridged by 2,6-dichlorobenzoic acid

作者：Zhang Chun Hua^*; Tang Si Ping; Chen Man Sheng; Kuang Dai Zhi; Deng Yi Fang

来源：Chinese Journal of Inorganic Chemistry, 2008, 24(9): 1519-1522.

• manganese complex
• crystal structure
• 2,6-dichlorobenzoic acid
• hydrothermal synthesis

A dinuclear manganese(II) complex, [Mn-2(L-1)(2)(phen)(4)]center dot(ClO4)(2) (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.1123(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, alpha=93.768(2)degrees, beta=90.606(10)degrees, gamma=95.606(3)degrees, V=3.174 8(15) nm(3), Z=2, C62H38Cl6Mn2N8O12, M-r=1 409.58, D-c=1.475 g.cm(-3), mu=0.718 mm(-1), F(000)=1 428, R= 0.064 3, wR =0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry.

• 出版日期2008-9
• 单位衡阳师范学院