Adhesion enhancement of titanium nitride coating on aluminum casting alloy by intrinsic microstructures

作者：Nguyen Chuong L^*; Preston Andrew; Tran Anh T T; Dickinson Michelle; Metson James B

来源：Applied Surface Science, 2016, 377: 174-179.

DOI：10.1016/j.apsusc.2016.03.117

• Titanium nitride
• Coating adhesion
• Aluminum alloys
• Nano-indentation
• Ion-assisted deposition

Aluminum casting alloys have excellent castability, high strength and good corrosion resistance. However, the presence of silicon in these alloys prevents surface finishing with conventional methods such as anodizing. Hard coating with titanium nitride can provide wear and corrosion resistances, as well as the aesthetic finish. A critical factor for a durable hard coating is its bonding with the underlying substrate. In this study, a titanium nitride layer was coated on LM25 casting alloy and a reference high purity aluminum substrate using Ion Assisted Deposition. Characterization of the coating and the critical interface was carried out by a range of complementing techniques, including SIMS, XPS, TEM, SEM/EDS and nano indentation. It was observed that the coating on the aluminum alloy is stronger compared to that on the pure aluminum counterpart. Silicon particles in the alloy offers the reinforcement though mechanical interlocking at microscopic level, even with nano-scale height difference. This reinforcement overcomes the adverse effect caused by surface segregation of magnesium in aluminum casting alloys.

• 出版日期2016-7-30