Photosalient Effect of a Diarylethene with a Perfluorocyclohexene Ring

作者:Hatano Eri; Morimoto Masakazu*; Hyodo Kengo; Yasuda Nobuhiro; Yokojima Satoshi; Nakamura Shinichiro; Uchida Kingo*
来源:Chemistry - A European Journal, 2016, 22(36): 12680-12683.
DOI:10.1002/chem.201603020

摘要

Crystals of a diarylethene with a perfluorocyclohexene ring exhibit a remarkable photosalient effect upon UV light irradiation that is attributed to the structural changes that occur when going from open-to closed-ring isomers in the crystalline state, together with the existence of two conformers with different photoconversions compared with those of a perfluorocyclopentene derivative. Our current results give a design principle for molecular structures so as to achieve the photosalient effect for photochromic crystals.

  • 出版日期2016-8-26