Nitroxyl radical self-assembled monolayers on gold: Experimental data vs. Laviron's interaction model

作者：Aleveque Olivier; Blanchard Pierre Yves; Breton Tony^*; Dias Marylene; Gautier Christelle; Levillain Eric; Seladji Fawzia

来源：Electrochemistry Communications, 2009, 11(9): 1776-1780.

DOI：10.1016/j.elecom.2009.07.015

• Tempo
• Self assembled monolayers
• Cyclic voltammetry
• Interaction model

Mixed SAMs of nitroxyl radical derivative and alkanethiol have been studied by cyclic voltammetry in both aqueous and non-aqueous solvents. Cyclic voltammograms exhibit shapes as a function of surface coverage deviating from an "ideal system". Confronted to Laviron's interaction model, the agreement observed between theory and experiments provides evidence of a random distribution of electroactive centers on surface and indicates that the local ionic environment of charged redox centers plays a major role in the electrochemical behaviour of SAMs.

• 出版日期2009-9