Analyzing fluorophore electronic structure and depolarization by fluorescence polarizing angle spectrum

作者:Mu, Taotao; Chen, Siying*; Zhang, Yinchao; Chen, He; Guo, Pan
来源:Applied Physics Letters, 2014, 105(3): 031110.
DOI:10.1063/1.4890860

摘要

In this Letter, a method, based on stokes parameters, is developed to observe the angular displacement between the excitation and emission moments. Experiments demonstrate that when combined with degree of polarization spectrums, we can acquire the depolarization caused by angular displacement or energy migration. The method presented in this Letter can be easily realized with the existing fluorescence measuring system and may potentially make it convenient to study the fluorophore electronic structure or the mechanism of fluorescence anisotropy.