Avoiding Magnetochemical Overparametrization, Exemplified by One-Dimensional Chains of Hexanuclear Iron(III) Pivalate Clusters

作者：Baca Svetlana G; Secker Tim; Mikosch Annabel; Speldrich Manfred; van Leusen Jan; Ellern Arkady; Koegerler Paul

来源：Inorganic Chemistry, 2013, 52(8): 4154-4156.

DOI：10.1021/ic4003884

One-dimensional chain coordination polymers based on hexanuclear iron(III) pivalate building blocks and 1,4-dioxane (diox) or 4,4%26apos;-bipyridine (4,4%26apos;-bpy) bridging ligands, [Fe6O2(O2CH2)(O2CCMe3)(12)(diox)](n) (1) and [Fe6O2(O2CH2)(O2CCMe3)(12)(4,4%26apos;-bpy)](n), (2), showcase the utility of the angular overlap model, implemented in the program wxJFinder, in the predictive identification of the relative role of intra- and intercluster coupling.

• 出版日期2013-4-15