科研之友
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摘要
Although the lithium-sulfur battery exhibits high capacity and energy density, the cycling performance is severely retarded by dendrite formation and side-reactions of the lithium metal anode and the shuttle effect of polysulfides. Therefore, exploring lithium rich-alloy (or compound) anodes and suppressing the shuttling of polysulfides have become practical technical challenges for the commercialization of lithium-sulfur batteries. Here, a lithium ion sulfur full battery system combining a lithium-rich Li-Si alloy anode and sulfurized polyacrylonitrile (S@pPAN) cathode has been proposed. The free-standing CNF matrix supported Li-Si alloy anode is prepared by a simple and effective method, which is practical for scale-up production. The obtained Li-Si alloy anode demonstrates high cycling stability without dendrite growth, while the use of the S@pPAN cathode avoids the shuttle effect in carbonate electrolytes. The constructed Li-Si/S@pPAN battery could be cycled more than 1000 times at 1C and 3000 times at 3C, with a capacity fading rate of 0.01% and 0.03% per cycle. The exceptional performance should originate from the stable integrated anode structure and the excellent compatibility of the S@pPAN cathode and Li-Si alloy anode with carbonate electrolytes.
- 出版日期2018-12-21
- 单位上海交通大学
