A self-assembled monolayers assisted solid-state conversion of boehmite particles to aluminum oxide film

作者:Sakuragi Naoko; Yamamoto Shintaro; Koide Yoshihiro*
来源:Journal of the American Chemical Society, 2007, 129(33): 10048-+.
DOI:10.1021/ja068981o

摘要

An aluminum oxide coating film is prepared for the first time by a solid-state conversion of boehmite (AlOOH center dot n H2O) particles, which are covalently attached on self-assembled monolayers (SAMs) of 11-mercaptoundecanoic acid (MUA) built on Au layer. The particles held on MUA SAMs are subject to sintering at elevated temperatures to fuse into monolithic film. X-ray photoelectron spectroscopy confirmed the existence of the hexacoordinate Al atoms. Fabrication steps are monitored by atomic force microscopy.

  • 出版日期2007-8-22