mu-Oxido-bis({4,4 '-dibromo-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}chromium(III))

作者:Liu Ying*; Dou Jianmin; Niu Meiju; Zhang Xianxi
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M3032-U1559.
DOI:10.1107/S1600536807057996

摘要

In the title compound, [Cr-2(C16H12Br2N2O2)(2)O], Cr-III is chelated by a Schiff base ligand through two N and two O atoms, and is pentacoordinate, with a bridging oxide ion. The coordination geometry can be described as square-based pyramidal, with the bridging oxide in the apical site, giving the shortest bond. The bridging ligand lies on a crystallographic twofold rotation axis.