科研之友
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摘要
A rapid and highly sensitive method is described for the extraction and determination of di- and tributyltin in PVC samples using headspace liquid phase microextraction followed by an analysis with graphite furnace atomic absorption spectrometry (HS-LPME/GFAAS). The analytes were derivatized in situ with sodium tetraethylborate and concentrated in a 2 mu l microdrop of benzyl alcohol suspended from the tip of a conventional GC microsyringe. The ethylated species then were directly transferred into a graphite furnace and quantified. The extractions were carried out for 5 ml sample solution (8 ml vial) adjusted at pH 5, with derivatization at 22 degrees C for 15 min in a 2% sodium tetraethylborate. The experimental parameters impacting the performance of HS-LPME were also investigated. According to the analysis, the linearity range was from 5.0 to 250.0 ng l(-1) with a detection limit of 0.5 ng l(-1) for dibutyltin and from 1.7 to 170.0 ng l(-1) with a detection limit of 0.17 ng l(-1) for tributyltin. Method RSD values were below 1.5%. Finally, the analysis of spiked PVC and water samples revealed that matrix had little effect upon extraction
- 出版日期2011-6
