Ab initio Study of New Phosphino PCP Pincer Ligand, {C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)}

作者：Naghipoor Ali^*; Ghasemi Zahra Haji; Abbasi Shahryar

来源：Asian Journal of Chemistry, 2009, 21(4): 2573-2576.

• Ab initio study
• Phosphino PCP pincer ligand

Multidentate ligand systems, both cyclic and acyclic can be designed to bind transition metals in a predictable manner. The steric constraints of such ligands and the nature of the donor atoms determine to a large extent the stability and properties of the metal complexes. Here in. the new PCP pincer ligand, {C6H4-1-(CH2PPh2)-3-(CH(CH3)PPh2)}, has been theoretically studied by ab initio restricted Hartree-Fock (RHF).

• 出版日期2009-4