A Heterometallic MOC Assembled from Cobalt-bisupported Keggin Subunits

作者：Liu, Heng; Guo, Ying; Ran, Rui; Ma, Huiyuan^*; Pang, Haijun; Zhang, Huiqiu; Zhao, Chunyan

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2013, 68(11): 1214-1218.

DOI：10.5560/ZNB.2013-3124

• Polyoxometalate
• Tungstoborates
• Cobalt

A heterometallic metal-organic complex (MOC), K[Co(1,10-phen)(2)(H2O)](2)[BW12O40]center dot 2H(2)O (phen = 1,10-phenanthroline) (1), has been synthesized hydrothermally and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The complex exhibits cobalt-bisupported tungstoborate units and potassium cations. The luminescence of the title complex has been investigated.

• 出版日期2013-11
• 单位哈尔滨学院; 黑龙江大学